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![]() The stabilization of the dispersed droplets within PEs is ensured by a strong adsorption of the solid particles at their surfaces. The stabilization of larger droplets (few millimeters diameter) is possible as well, using micron-sized solid particles. The solid particles that act as emulsifiers are of nanometric size, while the stabilized droplets are as small as few micrometers diameter. Both droplets and continuous phase contain different molecules (chemically incompatible macromolecules, for instance), which are entirely water-soluble. Also, PEs may be water-in-water (W/W) emulsions, which are dispersions formed by droplets of water-solvated molecules moving in another continuous aqueous solution. These particles may be organic or inorganic, according to the nature of their desired use. These dispersions are stabilized by an addition of small solid particles that act as emulsifiers, instead of the surfactant molecules. Pickering emulsions (PEs), are dispersions presenting, very often, as oil-in-water (O/W), water-in-oil (W/O) or double emulsion water-oil-water (W/O/W). Finally, we precise the major role played by grafted polymers onto the spherical oil/water interface. ![]() The question (3) is concerned with an exact study of the spherical diffusion of anchored nanoparticles on the surface of the dispersed oil-droplets. The question (2) deals with a quantitative investigation of the clothed oil-droplets dynamics (cage effect and subdiffusion), using a Generalized Langevin Equation, which is successfully tested by Molecular Dynamic Simulations. To this end, the adopted pair-potential is that of Sogami-Ise combining repulsive and attractive forces, and use is made of the so-called Integral Equation Method. For question (1), we recall the essential steps allowing the determination of the structure-factor and the spatial-correlation function, and the thermodynamic properties, as pressure, internal energy, and thermal compressibility of these emulsions. For the study, the emulsions are regarded as colloidal solutions, where the clothed oil-droplets play the role of charged soft-colloids, and in addition, the adsorbed nanoparticles are assumed to be point-like. Here, we are concerned with three important questions: (1) Structure and thermodynamics of these emulsions, (2) cage effect and subdiffusion phenomenon within them, and (3) spherical diffusion of anchored nanoparticles on the curved oil/water interface. The findings in this research can provide further knowledge that can enhance the safe transportation of CO2 in pipelines under stable hydrate forming conditions.In this review paper, we report on some very recent findings dealt with the oil-in-water Pickering emulsions, stabilized by a strong adsorption of charged solid nanoparticles on the surface of the oil-droplets. Presently, there is a growing concern regarding the potential leakage of CO2 in pipelines (Lu et al., 2020 Wang et al., 2022 Wareing et al., 2016), which may escalate due to pipewall corrosion caused by hydrates (Obanijesu, 2012). Two shear stress regimes have been identified for hydrate sloughing and pipewall shedding in this study, with the latter resulting in higher shear stress on the pipewall. The conversion of the consumption rate of natural gas to hydrates was achieved using the equation proposed in the literature (Umuteme et al., 2022). The study shows that the simulated temperature contours align well with the reported hydrate deposition profile in gas pipelines (Di Lorenzo et al., 2018). We have deduced the presence of hydrates based on the stable temperature profile of natural gas hydrates along the pipeline model. In this study, a computational fluid dynamics (CFD) simulation approach is employed using a validated CFD model from the literature for predicting hydrate deposition rates (Umuteme et al., 2022), by applying a subcooling temperature to the pipe wall at hydrates-forming condition. While sloughing occurs within the deposit of hydrates, pipewall shedding is related to direct interaction of the gas phase with the thin layer of hydrates on the pipewall. ![]() Similarly, pipewall shedding by hydrates involves the direct interaction of hydrates with the pipeline inner surface, resulting in the detachment or removal of hydrate deposits from the pipewall. Hydrate sloughing is the peeling off of some hydrate deposits from the pipeline inner surface. The continuous flow assurance in subsea gas pipelines relies heavily on the assessment of temperature profile during hydrate sloughing and pipewall shedding caused by hydrates, with similar implications for carbon dioxide (CO2) transportation under hydrate-forming conditions. ![]() ![]() ![]() irregular changes in heart rate and rhythm.Between 25 mg and 150 mg is considered a low dose, according to a 2014 study.Įxisting data advises against the use of Seroquel as a sleep aid, citing additional risks beyond a lack of evidence. Its sedative effects are thought to be the most apparent at lower doses. The appropriate dosage of Seroquel for sleep has yet to be determined. This medication carries the risk of various side effects that could be harmful. More research is needed before we know how safe and effective Seroquel is for primary insomnia. The researchers concluded that Seroquel should be reserved for people with psychiatric disorders that occur alongside insomnia. Research from 2016 found that there is limited evidence of the effectiveness and safety of Seroquel for primary insomnia. Seroquel has also been increasingly prescribed for stand-alone (primary) insomnia due to its sedating properties. Health professionals commonly prescribe Seroquel off-label when insomnia is caused by another psychiatric disorder (secondary insomnia). Each also has the potential for considerable side effects. Each of these chemicals interacts with the nervous system to regulate mood and other important body functions. Seroquel is thought to work by modifying levels of chemicals like dopamine, serotonin, and histamine. Mental health professionals also sometimes prescribe it as a supplementary medication for major depressive disorder. Like other antipsychotic medications, it has been approved for mental health disorders, such as: It has not been approved by the Food and Drug Administration (FDA) for insomnia. Seroquel ( quetiapine) is considered a second-generation antipsychotic drug. ![]() ![]() In Moonstruck (1987), she plays a pessimistic Italian widow who believes in curses, specifically those pertaining to love. Katie Heaney, senior writer MoonstruckĪny movie with Cher is going to be good in my book, so let’s just get that part out of the way. It’s so funny and so sweet and not enough people have seen it. It’s great for so many reasons: the central romance is late middle-aged and accordingly complicated, and Sarandon’s pitch-perfect mom voice-mails kill me every time. My favorite feel-good rom-com is 2015’s The Meddler, starring Susan Sarandon and Rose Byrne. Brock Colyar, editorial assistant The Meddler And in case the aging Nicholson isn’t your thing, the movie features Keanu Reeves as a steamy doctor. The scene during which Keaton cries for days on end is Meyers at her best, portraying complex emotions for an age group that doesn’t always get the spotlight. This one is classic Nancy Meyers: beautiful kitchens with gargantuan islands, Diane Keaton in fantastic knitwear, and an affair between a playwright mother and her daughter’s much older, womanizing boyfriend (Jack Nicholson). Kerensa Cadenas, senior editor Something’s Gotta Give It’s a delightful watch and might make you consider attempting Judd’s perfect pixie cut on yourself. Judd plays a talk-show producer who gets dumped by her co-worker and creates a theory about how men always want the “new cow.” This being a rom-com, things of course spiral out of control, and she finds love right under her nose. Who hasn’t wanted to know why someone broke up with them? It’s a question that many never get a simple answer to, and this Ashley Judd rom-com explores exactly that. Adrienne Green, senior writer Someone Like You A lot more romance than comedy, and VERY ’90s, but a good throwback that earns its two hours. All of that holds up, but right now I love watching it because it’s nice to see all of the little mundane moments of life that feel out of reach right now: house parties, the satisfaction of curving a guy who shot his shot a little too hard, getting clowned by your friends at game night. It was lauded at the time for showcasing a different portrait of black life, one that wasn’t surrounded by violence or focused on strife. ![]() It’s a simple film, set in Chicago’s jazz and spoken-word scene, about two artists - a young poet, played by Larenz Tate, and a photographer, played by Nia Long - who fall in love and struggle to stay there. Kelly Conaboy, writer-at-large Love Jones You deserve it! The movie stars Charlize Theron as the United States secretary of State and Seth Rogen as a left-leaning Brooklyn journalist who becomes her speechwriter, and I know that might not sound convincing, but I promise that you will like it. Why are you waiting? Are you saving it for a special occasion? If so, I suggest forgoing that plan and just watching it now. It’s possible you still haven’t seen Long Shot, the best romantic comedy of 2019. Sangeeta Singh-Kurtz, senior writer Long Shot There’s also a really good paintball makeout scene. It was filmed in my hometown, which would usually be a turnoff, but other than that it’s a perfect movie: Ledger sings “Can’t Take My Eyes Off You,” Allison Janney is a principal who writes erotica, and a teenage Joseph Gordon-Levitt plays Ledger’s scrawny sidekick. Based loosely on The Taming of the Shrew, it sees a beautiful Heath Ledger opposite a super-grumpy Julia Stiles (the movie opens with her reading The Bell Jar). But my desert-island rom-com has to be 10 Things I Hate About You. There were so many excellent rom-coms released this year: Alice Wu’s The Half of It comes to mind first, as does this weird little British film, Love Wedding Repeat. Izzy Grinspan, deputy style editor 10 Things I Hate About You It’s very sweet and has a much more satisfying ending than How I Met Your Mother. ![]() You see him courting three women in flashbacks, but you don’t get to find out which one he married until the end. The premise is that Ryan Reynolds is telling his daughter how he fell in love with her mother. Rachel Bashein, managing editor Definitely, Maybe The 1995 remake with Julia Ormond and Harrison Ford is very good too. There’s identity confusion, physical comedy, a tennis-court dance, and the perfect deployment of “La Vie en Rose.” It just makes me happy. Billy Wilder directs Audrey Hepburn, William Holden, and Humphrey Bogart at the top of their games as they swap longing gazes and witticisms. Not the most groundbreaking recommendation, I know, but it’s stood the test of time for a reason. ![]() ![]() ![]() Turning even your most ridiculous ideas into reality. More than just simple upgrade and tunning, you can gain access to all the customizing options in the Garage. ![]() Visit the Garage to get some awesome custom parts for your carĪnd if you’re thinking of building your own dream vehicle using only custom parts, the Garage will be the best place for you to make that dream come true. Experience smooth and satisfying hill climbing adventures with Hill Climb Racing. Enjoy the game as you play it on different resolutions. On top of that, the game also features a well-optimized gameplay that allows it to be relatively stable on different devices with varied hardware. Well-optimized gameplay to ensure satisfying experiences Each terrain will introduce a completely different gameplay compared to the others. Drive to multiple places and have your vehicles tested on different surfaces. Moreover, in Hill Climb Racing, players will be introduced to the endless journey through varied locations. Enjoy your ride in dozens of different tracks Have an improved engine, suspension, new tires, and so on. Choose your favorite vehicles out of several models and pick the right upgrades that you want to have on them. Your cars can also receive multiple upgrades and tunning that could make them more effective during your ride. Collect resources for multiple car upgrades Prove to the world that anyone can be a hill climbing driver. Ride on your good old trucks, motorbikes, snow breaker, or even climb on a sleigh that is pulled by a bunch of reindeer. Ride on your favorite vehiclesĪnd to make the hill climbing sessions even more exciting, you’ll have access to dozens of different vehicles. 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Here you’ll find all the exciting features that the game has to offer: Enjoy the complete portable gameplay In addition, the cars will also need to be refueled in certain stages to ensure that they still function properly. And his fragile neck won’t be able to handle all the fuzz. Upgrade your cars to give them even more powers and abilities.īut don’t push it too far without proper considerations as you’ll need to protect your beloved Bill from serious injuries. Perform daring tricks to earn yourself additional bonuses and points. Climb on different surfaces as you try your best on varied vehicles. The game also features dozens of different challenges that you could take on during your journey. ![]() Explore the incredible laws of physics as Bill beat the incredible racing levels and set his records. Race on your beloved vehicle to the places that no one ever dares to set foot on. Make your marks on the world most famous hill racing locations from the Ragnarok mountains to an abandoned Nuclear Plant. Take Bill to the local racing hill and this will be your first start. And to do that, he’s going to need your help to get to his goal. Join Newton Bill, the young and daring uphill racer who’ve always dreamed of being the world most successful hill racer. The game introduces gamers to the world of hill racing where you’ll have the opportunities to explore all the amazing aspects of the sport. Find out more about this amazing game with our reviews. Get involved in the addictive racing experiences with Hill Climb Racing. Begin your racing career as a daring young man, take on varied hillclimbing challenges with your old cars and unlock new features with it. Take a few days away from your regular racing game that you’ve been too familiar with and spend some quality times in this oddly satisfying game from Fingersoft. Regular updates and fixes to ensure the most satisfying experiences.Visit the Garage to get some awesome custom parts for your car.Well-optimized gameplay to ensure satisfying experiences.Enjoy your ride in dozens of different tracks.Collect resources for multiple car upgrades.Addictive physics that not like any others. ![]() ![]() ![]() If the serial number begins with an "L" followed by 5 digits, your guitar was likely made between 19. If the serial number on your Jazzmaster is 5 digits between 3009, your Jazzmaster may have been made between 19. Here's a good resource for vintage Fender serial numbers: Fender Serial Numbers.įender Jazzmaster serial numbers are found on the back of the guitar on the neck plate from 1958 until 1977. Fender guitar collectors are looking for Jazzmasters that have all their original parts so it's best if the year indicated by the serial number matches the rest of the guitar. Still, they're an important first step in finding the year it was made. Fender Serial Numbersįender serial numbers are not the most reliable way to date a vintage Jazzmaster since they're style specific, not necessarily consecutive, and they're easily swapped for a different number using only a screwdriver. Martin Kelly and Terry Foster put together an amazing resource for all vintage Fender guitars made during the golden era for the company. If you're interested in more information about Jazzmasters then I recommend this book: Fender: The Golden Age 1946-1970. You can also contact me here: Sell a Fender Jazzmaster. I'm looking forward to checking out your vintage Jazzmaster. You can contact me at the button below or send pictures to the contact information at the bottom of this page. If you've considered selling your Jazzmaster and are looking for a passionate Fender collector then I may be the one you're looking for. I'm always on the hunt for nice examples of vintage Fender Jazzmaster guitars. If you think you have a vintage Fender Jazzmaster from the 1950s, 1960s, or 1960s and are looking for help with how to date it then you can contact me at the red button below. I want you to know what a Fender guitar expert looks for to find the year of a Fender Jazzmaster so you can feel confident enough to sell it. Fender guitar collectors look at each aspect of the guitar to find out if all parts of the Jazzmaster match to the same year. Fender debuted the Jazzmaster model in 1958 and slowly updated the model through the late 1950s, 1960s, until discontinuing the model for a few years in the late 1970s. Knowing how to date a Fender Jazzmaster is the first step in finding out how much it's worth. ![]() ![]() ![]() Viscoelastic properties absorb shock and distribute stress evenly for bonding power that helps eliminate mechanical fastening in many jobs. 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Please note that mailing lists are independent from each other. With the ability to join a variety of materials including aluminum, steel, glass, plastics and painted and powder-coated surfaces, they provide resilient. That way they’ll be able to remove your email address from the mailing list, should you request us to do so. These high-strength, double-sided acrylic foam tapes let you quickly and easily create a long-lasting bond that actually builds strength over time. Some members of our staff can view mailing lists with email addresses.
![]() ![]() Represents the number of ways of selecting $k$ objects from a set of $n$ objects when repetition is permitted.Įxample. ![]() ![]() In this case, we are selecting the subset of $k$ boxes which will be filled with an object. Since the order in which the members of the committee are selected does not matter, the number of such committees is the number of subsets of five people that can be selected from the group of twelve people, which isĪlso counts the number of ways $k$ indistinguishable objects may be placed in $n$ distinct boxes if we are restricted to placing one object in each box. In how many ways can a committee of five people be selected from a group of twelve people? Permutations are different from combinations, as the order matters in permutations.Ĭombinations are useful in solving problems in different fields, such as statistics, probability, and computer science.Is the number of ways of selecting a subset of $k$ objects from a set of $n$ objects, that is, the number of ways of making an unordered selection of $k$ objects from a set of $n$ objects.Įxample. The formula for combinations is nC r = n! / (r! * (n-r)!) Key TakeawaysĬombinations are arrangements of a set of objects in which the order is not important. Therefore, the formula for combinations is nC r = n! / (r! * (n-k)!), which gives the number of possible ways to choose k objects from a set of n objects without considering the order of selection. Using the definition of factorials, this can be further simplified as: Using the multiplication principle, the total number of ways to choose k objects from a set of n objects is: To find the number of possible combinations, we can use the following approach:Ĭhoose the second object in (n-1) ways, as one object has already been selected.Ĭhoose the third object in (n-2) ways, as two objects have already been selected.Ĭontinue this process until r objects have been selected. Suppose we have a set of n distinct objects, and we want to choose r objects from this set without considering the order of selection. The formula for combinations can be derived using the principles of counting and factorials. Permutations with Repetition These are the easiest to calculate. How many possible ways are there to distribute the party favors?ĨC 4 = 8! / (4! * (8-4)!) = 70 Proof of the Formula for Combinations Suppose you have eight different party favors, and you want to distribute them among four guests. There are 120 possible combinations that can be set on the lock. How many possible combinations are there? There are 210 possible committees that can be formed.Ī combination lock has three dials, each numbered from 0 to 9. How many possible committees can be formed? Suppose there are ten people in a group, and you want to select a committee of four people. Therefore, there are 20 possible combinations of three books that can be selected from a set of six. The formula is given as:įor example, if you have six books and you want to select any three of them, the number of possible combinations is: ![]() The formula for combinations is expressed as nC k, where n is the total number of objects in the set, and r is the number of objects selected. The formula for permutations is different from that for combinations. For instance, if you have the same set of five fruits and want to select any three, the selection will be a permutation, and the order in which you select them will matter. Permutations are different from combinations, as the order matters in permutations. The number of possible combinations that can be made from a set is determined by a formula. Permutations are specific selections of elements within a set where the order in which the elements are arranged is important, while combinations involve the selection of elements without regard for order. In other words, combinations are arrangements of a set of objects in which the order is not important.įor example, if you have five different fruits, say an apple, a banana, an orange, a mango, and a pear, and you want to select any three of them, the selection will be a combination, and the order in which you select them will not matter. ![]() ![]() She also undertook several curatorial projects, including Kingdom of the Sun: Indian Court and Village Art from the Princely State of Mewar (Asian Art Museum, San Francisco, 2007). Turning to debates on the category of the folk in South Asia, The Two-Headed Deer focused on narrative strategies that were mobilized by Orissan artists to visualize the epic. Based on extensive fieldwork, The Art of Gupta India offered a groundbreaking analysis of Indian sculpture and architecture of the fourth and fifth centuries. Her distinguished career extended over four decades and included landmark publications such as The Art of Gupta India: Empire and Province (1982) and The Two-Headed Deer: Illustrations of the Rāmāyaṇa in Orissa (1996). Williams joined the faculty at UC Berkeley in 1967, where she held a joint appointment in the Departments of History of Art and South and Southeast Asian Studies. from Harvard University for her dissertation titled Buddhist Wall Paintings of Khotan (1969). from Swarthmore College in 1960 and a M.A. ![]() Born in southern Indiana, Williams received a B.A. She was one of the foremost scholars of South and Southeast Asian art and architecture and, indeed, one of the most well-regarded for her seminal work on fourth- and fifth-century sculpture and architecture as well as later folk traditions. Williams, distinguished scholar of South and Southeast Asian art, passed away at her home in Berkeley on June 16, 2022, at the age of eighty-four. 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